1,4-Diazoniabicyclo[2.2.2]octane diaquadichlorido(oxalato-κ2 O,O′)iron(III) chloride
نویسنده
چکیده
In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.
منابع مشابه
1,4-Diazoniabicyclo[2.2.2]octane terephthalate
In the title compound, C(6)H(14)N(2+)·C(8)H(4)O(4) (2-), the protonated 1,4-diazo-niabicyclo-[2.2.2]octane cations and the deprotonated terephthalate anions are alternately linked by N-H⋯O hydrogen bonds into chains.
متن کامل1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate)
In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. The 1,4-diazo-niabicyclo-[2.2.2]octane cation is located about a twofold rotation axis. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network.
متن کامل1-Bromomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridozincate
The reaction of 1-bromo-methyl-1,4-diazo-niabicyclo-[2.2.2]octane bromide, zinc chloride and hydro-chloric acid in water yields the title compound, (C(7)H(15)BrN(2))[ZnCl(4)]. In the crystal, the components are linked by N-H⋯Cl hydrogen bonds. The Zn(II) atom has an approximately tetra-hedral coordination geometry.
متن کامل1,4-Diazoniabicyclo[2.2.2]octane tetrachloridozincate monohydrate
In the title compound, (C(6)H(14)N(2))[ZnCl(4)]·H(2)O, the crystal packing is governed by an extensive three-dimensional network of N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds. The zinc(II) metal centre has a slightly distorted tetra-hedral coordination geometry.
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)
In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra-hedral geometry. Each [MnCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001].
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